Product ID:FREON 11A & FREON 11C
MSDS Date:05/01/1989
FSC:6830
NIIN:00N020022
MSDS Number: BLHQY

E I DUPONT DE NEMOURS & CO

CHESTNUT RUN PLAZA
WILMINGTON, DE 19880-0709
US

Emergency Phone: 302-999-5072

Info Phone: 302-999-5072

Preparer: K P BROWN

Cage: 0ERJ7

E.I. DUPONT DE NEMOURS & CO

WILMINGTON, DE 19898 US

Telephone: 800-441-7515;800-441-9442

Cage: 18873

EFTS OF EXCLUSION OF O*2 W/GROSSLY EXCESSIVE

RTECS: 9999999ZZ

HAVE PRODUCED SENSIT OF MYOCARDIUM TO EPINEPHRINE IN

RTECS: 9999999ZZ

ADRENOMIMETICS (E.G.,EPINEPHRINE) MAY BE

RTECS: 9999999ZZ

ACUTELY OR CHRONICALLY EXPOSED TO CHLOROCARBONS OR

RTECS: 9999999ZZ

IN SITUATIONS OF EMERGENCY LIFE SUPPORT.

RTECS: 9999999ZZ

SHOULD BE USED IN LOW PLACES. USE EXPLOSION- PROOF

RTECS: 9999999ZZ

TRICHLOROFLUOROMETHANE (CFC-11) (SARA III)

CAS: 75-69-4

RTECS: PB6125000

Fraction By Weight: SEE ING

OSHA PEL 1000 PPM

ACGIH TLV: C, 1000 PPM; 9293

EPA Report Quantity: 5000 LBS

DOT Report Quantity: 5000 LBS

ALPHA-METHYL STYRENE

CAS: 98-83-9

RTECS: WL5075300

OSHA PEL 50 PPM/100 STEL

ACGIH TLV: 50 PPM/100 STEL;9192

LD50 LC50 Mixture:LD50:(ORAL,RAT)>4000 MG/KG.
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO
Health Hazards Acute and Chronic:INHAL OF HIGH CONCS OF VAP IS HARMFUL
& MAY CAUSE HEART IRREGS, UNCON/DEATH. INTENTIONAL MISUSE CAN BE
FATAL. VAP REDUCES O2 AVAIL FOR BRTHG & IS HEAVIER THAN AIR. CMPD
IS NOT SKIN IRRIT, MILD EYE IRR IT & UNTESTED FOR ANIMAL SENSIT.
TOX EFTS DESCRIBED IN ANIMALS FROM EXPOS BY INHAL INCLUDE CNS (SEE
EFTS OF OVEREXP)
Explanation of Carcinogenicity:NOT RELEVANT.
Effects of Overexposure:HLTH HAZ:EFTS & ANESTHETIC EFTS. CHGS IN LUNGS,
LIVER, BRAIN & SPLEEN WERE OBSERVED IN RATS RPTD EXPOSED BY INHAL
TO CONCS OF 12000PPM/GREATER. HUMAN HLTH EFTS OF OVEREXPOS:EYE:MAY
INCLUDE IRRIT W/DIS COMFORT, TEARING/BLURRING OF VISION. SKIN:CNTCT
W/LIQ MAY CAUSE DRYING W/RPTD CNTCT RESULTING IN MILD IRRIT (SUPP
DATA)
Medical Cond Aggravated by Exposure:INDIVIDUALS W/PRE-EXISTING DISEASES
OF THE CENTRAL NERVOUS OR CARDIOVASCULAR SYSTEM MAY HAVE INCREASED
SUSCEPTIBILITY TO TOXICITY OF EXCESSIVE EXPOSURES.

First Aid:INHAL:IMMED REMOVE TO FRESH AIR. KEEP CALM. IF NOT BRTHG,
GIVE ARTF RESP. IF BRTHG DFCLT, GIVE O2.CALL MD. SKIN:FLUSH
W/WATER. TREAT FOR FROSTBITE IF NEC. EYE:IMMED FLUSH W/PLENTY OF
WATER FOR AT LEAS T 15 MIN.CALL MD. INGEST:NOT CONSIDEREDPOTNTL RTE
OF EXPOS. NOTE TO MD:BECAUSE OF POSS DISTURB OF CARDIAC RHYTHM,
CATECHOLAMINE DRUGS,SUCH AS EPINEPHRINE,SHOULD BE USED W/SPECIAL
CAUTION (SEE ING 7)

Flash Point Method:TOC
Flash Point:NONE
Extinguishing Media:NONFLAMMABLE. USE MEDIA SUITABLE FOR SURROUNDING
FIRE .
Fire Fighting Procedures:WEAR NIOSH/MSHA APPROVED PRESSURE DEMAND SCBA
& FULL PROTECTIVE EQUIPMENT .
Unusual Fire/Explosion Hazard:DRUMS MAY RUPTURE UNDER FIRE CONDITIONS.
DECOMPOSITION PRODUCTS MAY INCLUDE CHLORIDES, FLUORIDES AND
PHOSGENE .

Spill Release Procedures:VENT AREA. DO NOT FLUSH INTO SEWERS. DIKE
SPILL. COLLECT ON ABSORB MATL & TRANSFER TO STEEL DRUMS FOR
RECOVERY OR DISPOSAL. COMPLY W/FEDERAL, STATE & LOCAL REGULATIONS
ON REPORTING RELEASES.
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.

Handling and Storage Precautions:STORE IN CLEAN, DRY AREA. DO NOT HEAT
ABOVE 125F.
Other Precautions:NO SMOKING IN AREA OF USE. DO NOT USE IN THE GENERAL
VICINITY OF ARC WELDING, OPEN FLAMES OR HOT SURFACES. HEAT AND/OR
UV RADIATION MAY CAUSE THE FORMATION OF CHLORIDES, FLUORIDES AND/OR
PHOSGENE (FP N).

Respiratory Protection:UNDER NORMAL MANUFACTURING CONDITIONS, NO
RESPIRATORY PROTECTION IS REQUIRED WHEN USING THIS PRODUCT.
NIOSH/MSHA APPROVED SCBA IS REQUIRED IF LARGE RELEASE OCCURS.
Ventilation:NORMAL VENT FOR STD MFG PROCEDURES GEN ADEQ. LOCAL EXHAUST
SHOULD BE USED WHEN LG AMTS RELEASED. MECH VENT (SEE ING 8)
Protective Gloves:LINED BUTYL GLOVES.
Eye Protection:CHEMICAL WORKERS GOGGLES .
Other Protective Equipment:NONE SPECIFIED BY MANUFACTURER.
Work Hygienic Practices:NONE SPECIFIED BY MANUFACTURER.
Supplemental Safety and Health
MATLS TO AVOID:CATALYSTS SUCH AS ALCL3 & FECL3. EFTS OF
OVEREXP:W/DISCOMFORT/RASH. INHAL:MAY CAUSE TEMPORARY NERVOUS SYS
DEPRESS W/ANESTHETIC EFTS SUCH AS DIZZ, HDCH, CONFUSION, INCOORD, &
LOSS OF CON SCIOUS; TEMPORARY ALTERATION OF HEART'SELEC ACTIVITY
W/IRREG PULSE, PALPITATIONS/INADEQ CIRCULATION, OR (SEE ING 3)

HCC:N1
Boiling Pt:B.P. Text:75.0F,23.9C
Vapor Pres:792 @ 77F
Vapor Density:4.9
pH:NEUT
Evaporation Rate & Reference:0.1 (CCL4 = 1).
Solubility in Water:0.1% BY WT @ 77F.
Appearance and Odor:CLEAR, COLORLESS LIQUID, SLIGHT ETHEREAL ODOR.
Percent Volatiles by Volume:100

Stability Indicator/Materials to Avoid:YES
ALKALI OR ALKALINE EARTH METALS, POWDERED AL, ZN, BE, ETC. AVOID CNTCT
W/ACIDS, BASES, OXIDIZING AGENTS & (SUPP DATA)
Stability Condition to Avoid:OPEN FLAMES & HIGH TEMPERATURES.
Hazardous Decomposition Products:HIGH TEMPS CAN FORM HYDROCHLORIC &
HYDROFLUORIC ACIDS, POSS CARBONYL HALIDES, CHLORIDES, FLUORIDES AND
PHOSGENE .

Waste Disposal Methods:EPA HAZARDOUS WASTE NO. U121; F001; F002. COMPLY
W/FEDERAL, STATE & LOCAL REGULATIONS. RECLAIM BY DISTILLATION OR
REMOVE TO PERMITTED WASTE DISPOSAL FACILITY.

Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.